Vibrational Assignments
- Page ID
- 4435
\( \newcommand{\vecs}[1]{\overset { \scriptstyle \rightharpoonup} {\mathbf{#1}} } \) \( \newcommand{\vecd}[1]{\overset{-\!-\!\rightharpoonup}{\vphantom{a}\smash {#1}}} \)\(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\) \(\newcommand{\id}{\mathrm{id}}\) \( \newcommand{\Span}{\mathrm{span}}\) \( \newcommand{\kernel}{\mathrm{null}\,}\) \( \newcommand{\range}{\mathrm{range}\,}\) \( \newcommand{\RealPart}{\mathrm{Re}}\) \( \newcommand{\ImaginaryPart}{\mathrm{Im}}\) \( \newcommand{\Argument}{\mathrm{Arg}}\) \( \newcommand{\norm}[1]{\| #1 \|}\) \( \newcommand{\inner}[2]{\langle #1, #2 \rangle}\) \( \newcommand{\Span}{\mathrm{span}}\)\(\newcommand{\AA}{\unicode[.8,0]{x212B}}\)
Pr(-) | Pfr (+) | Assignment | Ref |
2557 | 2575 | \(Cys, \ \nu (S-H)\) | 1 |
1736 | 1724 | \(\nu (C_1=O)\) | 1,2,3,4,6 |
1734 | 1722 | \(-COOH \ (Asp/Glu), \ \nu(C=O)\) | 1,2 |
1704 | \(\nu (C_{19}=O)\) | 1,2,3,4,6 | |
1692 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |
1687 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |
1683 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |
1672 | \(amide \ I \ (loop/turn)\) | 1 | |
1653 | \(amide \ I \ (\alpha -helical)\) | 1,2,3 | |
1653 | \(chromophore^* \ \delta (N-H)\) | 1 | |
1653 | \(chromophore^* \ \nu (C-C)\) | 1,3,4 | |
1631 | \(amide \ I \ (\beta -structure)/chromophore \ \nu (C=C)\) | 1,3,5 | |
1614 | \(amide \ I \ (\beta -structure)^* /chromophore \ \nu (C=C)\) | 1,3,5 | |
1606 | \(amide \ I \ (\beta -structure)^* /chromophore \ \nu (C=C)\) | 1,3,4 | |
1589 | \(chromophore \ \nu (C=C)\) | 1,3,4,6 | |
1570 | 1554 | \(amide \ II\) | 1,3,4,5,7,8,9 |
1537 | \(chromophore \ \nu (C=C) \ + \ \delta (N-H)/\nu (C-N) \ + \ \delta (N-H)\) | 1 | |
1491 | 1512 | \(chromophore \ \nu (C=C) \ + \ \delta (N-H)/\nu (C-N) \ + \ \delta (N-H)\) | 1 |
1487 | 1502 | \(Trp, \ \nu (C-N) \ + \ \delta (C-H) \ + \ \delta (N-H)\) | 1 |
1246 | \(chromophore \ \nu (C-N)\) | 1 | |
1244 | 1228 | \(Trp^* , \ \nu (C-C) \ + \ \delta (C-H)/HisH, \ \delta (CH_3) \ + \ \nu (C-N) \ + \ \delta (N-H)\) | 1 |
1223 | 1230 | \(chromophore \ \nu (C-N)\) | 1 |
1209 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 | |
1177 | 1172 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 |
1151 | 1163 | \(chromophore \ \nu (C-N)\) | 1 |
1134 | \(chromophore \ \nu (C-N)\) | 1 | |
1119 | \(chromophore \ \nu (C-N)\) | 1 | |
1109 | \(chromophore \ \nu (C-N)\) | 1 | |
1107 | 1099 | \(HisH, \ \nu (C-N)\) | 1 |
1085 | 1082 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 |
1072 | \(chromophore \ \nu (C-N)\) | 1 | |
- van Thor, J. J.; Fisher, N.; Rich, P. R. J. Phys. Chem. B 2005, 109, 20597
- Foerstendorf, H.; Lamparter, T.; Hughes, J.; Gartner, W.; Siebert, F. Photochem. Photobiol. 2000, 71, 655.
- Siebert, F.; Grimm, R.; Rudiger, W.; Schmidt, G.; Scheer, H. Eur. J. Biochem. 1990, 194, 921.
- Foerstendorf, H.; Mummert, E.; Schafer, E.; Scheer, H.; Siebert, F. Biochemistry 1996, 35, 10793.
- Andel, F., III; Murphy, J. T.; Haas, J. A.; McDowell, M. T.; van der Hoef, I.; Lugtenburg, J.; Lagarias, J. C.; Mathies, R. A. Biochemistry 2000, 39, 2667.
- Foerstendorf, H.; Benda, C.; Gartner, W.; Storf, M.; Scheer, H.; Siebert, F. Biochemistry 2001, 40, 14952.
- Mroginski, M. A.; Murgida, D. H.; von Stetten, D.; Kneip, C.; Mark, F.; Hildebrandt, P. J. Am. Chem. Soc. 2004, 126, 16734.
- Fodor, S. P.; Lagarias, J. C.; Mathies, R. A. Photochem. Photobiol. 1988, 48, 129.
- Fodor, S. P.; Lagarias, J. C.; Mathies, R. A. Biochemistry 1990, 29, 11141.