Vibrational Assignments
- Page ID
- 4435
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| Pr(-) | Pfr (+) | Assignment | Ref |
| 2557 | 2575 | \(Cys, \ \nu (S-H)\) | 1 |
| 1736 | 1724 | \(\nu (C_1=O)\) | 1,2,3,4,6 |
| 1734 | 1722 | \(-COOH \ (Asp/Glu), \ \nu(C=O)\) | 1,2 |
| 1704 | \(\nu (C_{19}=O)\) | 1,2,3,4,6 | |
| 1692 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |
| 1687 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |
| 1683 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |
| 1672 | \(amide \ I \ (loop/turn)\) | 1 | |
| 1653 | \(amide \ I \ (\alpha -helical)\) | 1,2,3 | |
| 1653 | \(chromophore^* \ \delta (N-H)\) | 1 | |
| 1653 | \(chromophore^* \ \nu (C-C)\) | 1,3,4 | |
| 1631 | \(amide \ I \ (\beta -structure)/chromophore \ \nu (C=C)\) | 1,3,5 | |
| 1614 | \(amide \ I \ (\beta -structure)^* /chromophore \ \nu (C=C)\) | 1,3,5 | |
| 1606 | \(amide \ I \ (\beta -structure)^* /chromophore \ \nu (C=C)\) | 1,3,4 | |
| 1589 | \(chromophore \ \nu (C=C)\) | 1,3,4,6 | |
| 1570 | 1554 | \(amide \ II\) | 1,3,4,5,7,8,9 |
| 1537 | \(chromophore \ \nu (C=C) \ + \ \delta (N-H)/\nu (C-N) \ + \ \delta (N-H)\) | 1 | |
| 1491 | 1512 | \(chromophore \ \nu (C=C) \ + \ \delta (N-H)/\nu (C-N) \ + \ \delta (N-H)\) | 1 |
| 1487 | 1502 | \(Trp, \ \nu (C-N) \ + \ \delta (C-H) \ + \ \delta (N-H)\) | 1 |
| 1246 | \(chromophore \ \nu (C-N)\) | 1 | |
| 1244 | 1228 | \(Trp^* , \ \nu (C-C) \ + \ \delta (C-H)/HisH, \ \delta (CH_3) \ + \ \nu (C-N) \ + \ \delta (N-H)\) | 1 |
| 1223 | 1230 | \(chromophore \ \nu (C-N)\) | 1 |
| 1209 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 | |
| 1177 | 1172 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 |
| 1151 | 1163 | \(chromophore \ \nu (C-N)\) | 1 |
| 1134 | \(chromophore \ \nu (C-N)\) | 1 | |
| 1119 | \(chromophore \ \nu (C-N)\) | 1 | |
| 1109 | \(chromophore \ \nu (C-N)\) | 1 | |
| 1107 | 1099 | \(HisH, \ \nu (C-N)\) | 1 |
| 1085 | 1082 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 |
| 1072 | \(chromophore \ \nu (C-N)\) | 1 | |
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