Vibrational Assignments 2
- Page ID
- 4434
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| Pr(-) | Pr (Raman) | Lumi-R(+) | Lumi-R (Raman) | Lumi-R* (Raman) | Pfr (+) | Pfr (Raman) | I* (Raman) | Assignment | Ref |
| 2557 | 2575 | \(Cys, \ \nu (S-H)\) | 1 | ||||||
| 1736 | 1724 | \(\nu (C_1=O)\) | 1,2,3,4,6 | ||||||
| 1738 | 1732 | \(C_1=O\) | 10,1 | ||||||
| 1735 | 1738 | \(C_1=O\) | 10 | ||||||
| 1734 | 1722 | \(-COOH \ (Asp/Glu), \ \nu(C=O)\) | 1,2 | ||||||
| 1704 | \(\nu (C_{19}=O)\) | 1,2,3,4,6 | |||||||
| 1720 | 1692 | \(C_{19}=O\) | 10,1 | ||||||
| 1716 | 1685 | \(C_{19}=O\) | 10 | ||||||
| 1692 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |||||||
| 1687 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |||||||
| 1683 | \(amide \ I \ (loop/turn)/propionate \ COOH, \ \nu (C=O)\) | 1 | |||||||
| 1672 | \(amide \ I \ (loop/turn)\) | 1 | |||||||
| 1653 | \(amide \ I \ (\alpha -helical)\) | 1,2,3 | |||||||
| 1653 | \(chromophore^* \ \delta (N-H)\) | 1 | |||||||
| 1653 | \(chromophore^* \ \nu (C-C)\) | 1,3,4 | |||||||
| 1631 | \(amide \ I \ (\beta -structure)/chromophore \ \nu (C=C)\) | 1,3,5 | |||||||
| 1614 | \(amide \ I \ (\beta -structure)^* /chromophore \ \nu (C=C)\) | 1,3,5 | |||||||
| 1606 | \(amide \ I \ (\beta -structure)^* /chromophore \ \nu (C=C)\) | 1,3,4 | |||||||
| 1589 | \(chromophore \ \nu (C=C)\) | 1,3,4,6 | |||||||
| 1614 | 1609 | \(C=C \ stretch\) | 11 | ||||||
| 1570 | 1554 | \(amide \ II\) | 1,3,4,5,7,8,9 | ||||||
| 1537 | \(chromophore \ \nu (C=C) \ + \ \delta (N-H)/\nu (C-N) \ + \ \delta (N-H)\) | 1 | |||||||
| 1491 | 1512 | \(chromophore \ \nu (C=C) \ + \ \delta (N-H)/\nu (C-N) \ + \ \delta (N-H)\) | 1 | ||||||
| 1487 | 1502 | \(Trp, \ \nu (C-N) \ + \ \delta (C-H) \ + \ \delta (N-H)\) | 1 | ||||||
| 1246 | \(chromophore \ \nu (C-N)\) | 1 | |||||||
| 1244 | 1228 | \(Trp^* , \ \nu (C-C) \ + \ \delta (C-H)/HisH, \ \delta (CH_3) \ + \ \nu (C-N) \ + \ \delta (N-H)\) | 1 | ||||||
| 1223 | 1230 | \(chromophore \ \nu (C-N)\) | 1 | ||||||
| 1209 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 | |||||||
| 1177 | 1172 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 | ||||||
| 1151 | 1163 | \(chromophore \ \nu (C-N)\) | 1 | ||||||
| 1134 | \(chromophore \ \nu (C-N)\) | 1 | |||||||
| 1119 | \(chromophore \ \nu (C-N)\) | 1 | |||||||
| 1109 | \(chromophore \ \nu (C-N)\) | 1 | |||||||
| 1107 | 1099 | \(HisH, \ \nu (C-N)\) | 1 | ||||||
| 1085 | 1082 | \(chromophore \ \nu (C-C)/amino \ acid\) | 1 | ||||||
| 1072 | \(chromophore \ \nu (C-N)\) | 1 | |||||||
| 1345 | \(C-C \ ,C-N \ stretch\) | 11 | |||||||
| 1652 | 1643 | \(C_{15}=C_{16}\) | 10 | ||||||
| 1649 | 1633 | \(C_{15}=C_{16}\) | 10 | ||||||
| 1629 | \(C_{15}=C_{16} \ (methine \ bridge) \ ,C_{17}=C_{18} \ (double \ bond \ of \ the \ d \ ring)\) | 11 | |||||||
| 1652 | 1645 | \(C_4=C_5 \ (A-B \ ring) \ stretch\) | 11 | ||||||
| 1633 | 1627 | \(C_4=C_5\) | 10 | ||||||
| 1632 | \(C_4=C_5\) | 10 | |||||||
| 1635 | \(C_4=C_5\) | 10 | |||||||
| 1611 | 1602 | \(C_4=C_5, \ C_9=C_{10}, \ C_{10}=C_{11}, \ C_{15}=C_{16}\) | 10 | ||||||
| 794 | 803 | 816 | \(vinyl \ C_{15)-H \ hydrogen \ out-of-plane \ (HOOP)\) | 11 | |||||
| 1223 | 1056 | \(vinyl \ C-H \ in-plane \ rock\) | 11 | ||||||
| 1312 | \(vinyl \ N-H \ in-plane \ rock\) | 11 | |||||||
| 1566 | \(in-phase \ in-plane \ N-H \ rock \ (localized \ to \ B \ and \ C \ rings\) | 11 | |||||||
| 1560 | 1570 | \(N-H \ rock \ for \ C \ and \ D \ rings\) | 11 | ||||||
| 1302 | \(D-ring \ N-H rock\) | 11 | |||||||
| 1302 | \(N-H \ in-plane \ rock\) | 11 | |||||||
| 1112 | \(vinyl \ C-H \ rock\) | 11 |
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