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2.2: Hydrocarbons

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  • Hydrocarbons are organic molecules that consist exclusively, or primarily, of carbon and hydrogen atoms. They come in two flavors:

    • aliphatic hydrocarbons, which consist of linear chains of carbon atoms
    • aromatic hydrocarbons, which consist of closed rings of carbon atoms

    Aliphatic Hydrocarbons

    The simplest is methane, CH4. Next is ethane, C2H6.

    The fatty acids in fats are aliphatic hydrocarbons. If a chain holds all the hydrogen atoms it can, the molecule is said to be saturated. The fatty acids in tristearin are all saturated.

    If two adjacent carbon atoms each lose a hydrogen atom, a double bond forms between them. Such a molecule is said to be unsaturated.

    Example : Ethylene H2C=CH2

    The fatty acids in trilinolein and linolenic acid are examples of unsaturated fatty acids

    Aromatic Hydrocarbons

    The building block of aromatic hydrocarbons is the benzene ring. The arrangement of atoms is shown on the left. The version in the center is often used to simplify diagrams of molecular structures. The three double bonds are not restricted to the positions shown but are free to pass around the ring. This is sometimes indicated by drawing the benzene ring as it is on the far right.

    Some examples of biological molecules that incorporate the benzene ring:

    • the amino acids tyrosine and phenylalanine
    • cholesterol and its various derivatives, such as the sex hormones
      • estrogens
      • testosterone
    • the herbicide, 2,4-D

    The carotenoid, beta-carotene, is a hydrocarbon that has both aliphatic and aromatic portions.


    John W. Kimball. This content is distributed under a Creative Commons Attribution 3.0 Unported (CC BY 3.0) license and made possible by funding from The Saylor Foundation.